export@ezsteelpipe.com
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A mill-direct procurement playbook for superheater, reheater, steam generator, primary loop and once-through steam generator tubes that must survive 560 °C to 760 °C, 100,000-hour creep life and a 60-year in-service life — with a hard look at the σ-phase, M23C6 and 475 °C embrittlement risks that quietly shorten austenitic tube life.
Most pressure tubes sold for high-temperature service look identical on a mill test certificate: a 50 mm OD seamless tube, 8 mm wall, solution-annealed, with a heat number. The real differentiation lives in the chemical envelope — especially C, N, B, Ti, Nb, Cu and the Cu/(Ni+Cr) ratio — and in whether the tube can hold 100,000-hour creep rupture strength above 600 °C without long-term sigma-phase (σ) precipitation or M23C6 sensitization eating the grain boundaries.
This guide is written for:
We deliberately do not cover waterwall panels, economizer inlet tubes, condensate return lines, or firewater sprinkler risers — those are carbon steel pipe territory covered in a separate guide. And we don't cover finned tube or U-bend tube geometry — those are heat efficiency tubes territory.
Forget the textbook "18Cr-8Ni" label. For procurement, the eight families that matter at 560-760 °C are:
The choice between these is not just creep strength — it is also steam-side oxidation rate (which scales roughly with the parabolic rate constant kp at operating temperature), fireside corrosion allowance in coal/biomass boilers, σ-phase nose (the time-temperature-precipitation window where Cr-rich σ nucleates), and welding repairability after 100,000 h of service.
A Guangdong Power Grid study on TP304H boiler tubes after long-term high-temperature service in a 600 MW USC unit showed that the dominant failure mode was not creep rupture — it was M23C6 carbide precipitation on grain boundaries plus σ-phase precipitation in the matrix. Tensile strength and creep rupture life drop together as the chromium-depleted zone around the carbides grows.
Three operational factors accelerate this:
So the procurement question is not "can this tube reach 600 °C?" — most can. The question is "which tube holds 600 °C with a 6000-8000 start-stop cycle budget for 30 years?" That is where HR3C and Super304H outperform 304H, and where TP347HFG (fine-grain variant) outperforms standard 347H.
For procurement, the four major seamless austenitic boiler-tube standards that you will see in any tender are ASTM A213, EN 10216-5, GB/T 13296 and JIS G3463. For Russian/CIS projects add GOST 9941. For nuclear PWR steam generator tubes, ASME BPVC Section II Part B (SB-163, SB-167, SB-407) plus RCC-M Section II (M3301 / M3304 / M3401) are non-negotiable.
| Designation | ASTM / ASME | EN | JIS | GB | Max metal temp °C (typical) |
|---|---|---|---|---|---|
| TP304H / 18Cr-9Ni-C | A213 TP304H / SA-213 | EN 10216-5 1.4948 | JIS G3463 SUS304H TB | GB/T 13296 0Cr18Ni9 | ~600 (sensitization risk 500-700 °C) |
| TP316H / 16Cr-12Ni-2Mo | A213 TP316H / SA-213 | EN 10216-5 1.4918 | JIS G3463 SUS316H TB | GB/T 13296 0Cr17Ni12Mo2 | ~600 (better than 304H in coal-ash corrosion) |
| TP321H / 18Cr-10Ni-Ti | A213 TP321H / SA-213 | EN 10216-5 1.4541 | JIS G3463 SUS321H TB | GB/T 13296 0Cr18Ni10Ti | ~620 (Ti-stabilized, no IGC after weld) |
| TP347H / 18Cr-11Ni-Nb | A213 TP347H / SA-213 | EN 10216-5 1.4961 | JIS G3463 SUS347H TB | GB/T 13296 0Cr18Ni11Nb | ~620-650 (Nb-stabilized, post-weld no knife-line attack) |
| Super304H | A213 S30432 / ASME CC2328 | EN 10216-5 1.4904 (T/P) | — | — | 600-625 (3 % Cu + Nb-N creep boost, σ risk below 304H) |
| HR3C | A213 TP310HCbN / ASME CC2329 | EN 10216-5 1.4951 | — | — | 625-700 (25 Cr oxidation barrier, dense Cr2O3 scale) |
| Inconel 800H | B407 / SB-407 | EN 10216-5 1.4876 | — | GB/T 15062 0Cr20Ni32AlTi | ~700-760 (SMR, reformer, HTGR) |
| Inconel 690 (PWR SG) | B167 / SB-167 (TT-treatment) | EN 10216-5 2.4642 | — | — | ~350 (PWR SG tubing, primary stress-corrosion cracking) |
Some buyers still write "TP304 / 1.4301" because it is the cheapest. But standard TP304 (with C ≤ 0.08 %) is a low-carbon water-service grade, not a high-temperature creep grade. At 600 °C, the 100,000 h stress-rupture strength is roughly 50 % of TP304H (with C 0.04-0.10 %). Always specify the H suffix for any tube that operates above 525 °C continuously.
EN 10216-5 1.4948 has a tighter N specification and a different Ti/Nb balance than ASTM A213 TP304H. The "equivalent" label is approximate. For nuclear, ASME BPVC Section III requires the chemistry to be reported as heat-by-heat and the equivalence assessed by a Q-List reviewer, not by the trader.
TP347HFG (fine-grain, ASTM grain size 7 or finer) has 20-30 % better 100,000 h creep rupture strength than standard TP347H at 625 °C. If the spec sheet just says "TP347H", the mill will deliver coarse-grain. For final-stage superheater / reheater always write "TP347HFG" or "ASME CC2327" and add "ASTM grain size ≥ 7 per E112".
A spec from 2014 may not have referenced the ASME Section II Part D 2015 revision on long-term σ-phase data for HR3C and Super304H. If you are ordering for a 30-year life, the procurement specification must include the latest long-term creep / aging data tables — not the 100,000 h point, but the 200,000 h extrapolation envelope.
EN 10204 3.1 cert is signed by the mill's quality representative, independently of production. 3.2 cert is countersigned by an independent third-party inspector (SGS, Bureau Veritas, TÜV, DNV, etc.). For nuclear-class 1 / 2 / 3 pressure-retaining components, ASME BPVC Section III and RCC-M Section II both require 3.2. For utility boiler Section I, 3.1 is the default. Mixing the two up-front means re-issuing MTCs and a 4-6 week delay in delivery.
A high-temperature tube that is going to live at 600 °C for 30 years needs at least these eight items in its MTC and NDT dossier:
Add to that, for the first article / qualification lot only:
For standard austenitic grades (TP304H, TP316H, TP321H, TP347H) with a 6-12 month lead-time allowance, the mill-direct economics stack up roughly like this:
| Cost item | Mill-direct (sourced from a mill with full MTC, 3.1 / 3.2) | Stockist / trader |
|---|---|---|
| Unit price (TP304H, 50 OD × 8 mm) | Mill list price 100 % | Stockist list 120-150 % |
| MOQ (mill heat) | 5-20 t per size, 20-50 t per grade | 1 t or single tube |
| MTC fee (3.1 / 3.2) | 0.3-0.6 % of tube value (incl. in mill quote) | 1.0-1.5 % additional if re-issued |
| Lead time (in-stock) | 4-6 weeks from China mill | 1-2 weeks ex-warehouse |
| Lead time (custom heat / size) | 8-12 weeks standard austenitic; 10-14 weeks HR3C / Super304H | 14-20 weeks (mill re-route through stockist) |
| Logistics saving on full package (5-8 grades × 20-50 t) | 8-15 % of total package via bundled mill schedule | 0-5 % (no control over production lot) |
| Risk: wrong chemistry or missing heat-number traceability | Low (mill-controlled, single-mill single-MTC) | High (mix of mill batches, occasional sub-standard material) |
For HR3C, Super304H, Inconel 800H/800HT, Inconel 690, the lead time math flips: most stockists don't carry these in inventory, and the mill-direct 10-16 week wait is unavoidable. The right move is to commit to a forward order 6-9 months before erection starts, accept the mill-direct MOQ of 5-15 t, and combine HR3C + 800H + 690 in a single RFQ to amortize the mill's campaign-change cost.
Spec: TP347HFG or Super304H, OD 38-51 mm, wall 6-10 mm, solution-annealed, 100 % ECT + 1.5× hydrostatic, MTC 3.1, ASTM grain size ≥ 7. Avoid 304H in final-stage superheater; 304HFG can be used in primary superheater where metal temperature stays under 580 °C. For AUSC 700 °C pilot units, use HR3C for the highest-temperature section and Super304H for the intermediate.
Spec: Inconel 690 TT (thermally-treated) per ASME SB-167 or RCC-M M3301/M3304, OD 15.9-22.2 mm, wall 1.0-1.5 mm, Mill-Anneal (MA) or Stress-Relief-Anneal (SRA) condition depending on whether the unit is Westinghouse (MA) or Framatome / KEPCO (SRA). 100 % ECT + helium leak test, MTC 3.2 with independent third-party inspection (BIS, SGS, BV, TÜV, or French nuclear-authorized body). For older PWR unit retubing, sometimes TP304 / TP316 NG (Nuclear Grade) is still specified for compatibility with the original SG design.
Spec: Inconel 800H or 800HT per SB-407, OD 30-60 mm, wall 2-4 mm, solution-annealed at 1150-1200 °C, MTC 3.1, ECT + 1.5× hydrostatic, with extra requirement: no sulfur-bearing lubricant in cold-drawing (residual S must be ≤ 0.005 % post-pickling) because molten nitrate salt attacks residual S at 565 °C. Specify "low-S drawing lubricant" in the RFQ.
Spec: TP304H or TP347H per A213 + ASME Section III Subsection NB, OD 16-25 mm, wall 1.5-2.5 mm, solution-annealed, 100 % ECT, MTC 3.2, with extra requirement: elevated-temperature tensile at 525 °C and 575 °C per ASTM E21 included in first-article qualification. For higher-temperature SMR designs (Xe-100, IMSR, MMR), HR3C and Inconel 617 enter the picture and the lead time jumps to 16-24 weeks.
Spec: Inconel 800HT or HP-Mod (35Cr-45Ni-Mo-W) per ASTM B407 / B829, OD 60-114 mm, wall 6-12 mm, solution-annealed 1200-1240 °C for 800HT, with extra: creep-rupture test at 900 °C / 100 MPa, target life ≥ 100,000 h. Reformer tubes in ethylene crackers run 1050-1100 °C external, which is well above the envelope of any 18Cr-8Ni grade. Don't try to substitute 310S or 321H here; the creep strength drops an order of magnitude.
For the lower-temperature convection section (preheat, mixed-feed, steam superheat), 800H and 800HT dominate. For the bottom-of-convection steam-generation tubes, stainless steel pipe such as TP304H or 347H may suffice and reduce cost by 30-40 %.
Q1. Can I substitute TP321H for TP347H?
For 600 °C+ continuous service, no — TP347H (Nb-stabilized) holds 100,000 h rupture strength roughly 15-20 % better than TP321H (Ti-stabilized) because NbC is more stable than TiC at the grain boundary. For intermittent 540 °C service (e.g. chemical-process dryer tubes), TP321H is acceptable and 8-12 % cheaper. Always document the substitution with a Material Substitution Request (MSR) signed by both the design authority and the third-party inspector.
Q2. What is the real difference between Super304H and HR3C?
Super304H is an 18Cr-9Ni steel with 3 % Cu and a small Nb-N addition that boosts creep strength by fine Cu-rich and Nb(C,N) precipitates. It is the best choice for 600-625 °C. HR3C is a 25Cr-20Ni steel with Nb-N and roughly 2.5× the oxidation resistance of 304H at 650-700 °C because of the dense Cr2O3 layer. The trade-off: HR3C is roughly 2.5-3× the price per kg, harder to weld, and requires 1100-1180 °C solution anneal. Use Super304H as default for 600-625 °C; escalate to HR3C only where metal temperature exceeds 625 °C continuously.
Q3. Is Inconel 690 always required for PWR steam generator U-tubes?
For new-build PWR units since the 1990s, yes — 690 TT (thermally treated at 715 °C for 10-15 h after mill anneal) replaced Inconel 600 and Incoloy 800 because of stress-corrosion cracking (SCC) resistance in primary water. For SG retubing of older units, the choice is between 690 TT (best SCC, ~3-4× cost of 800) and 800NG (nuclear-grade, lower cost, acceptable SCC for moderate water chemistry). Some Korean and Chinese operators specify 690 NG (nuclear grade) with extra Ti + Mn control.
Q4. We need 80 t of TP347H in 10 weeks. Realistic?
It depends on the mill campaign. For a mill running TP347H already, 80 t can be delivered in 8-10 weeks (4 weeks production + 4-6 weeks sea-freight ex-China + 1-2 weeks port + inland). For a mill that needs to switch from 304H to 347H, add 3-4 weeks for campaign change. The honest answer: commit the RFQ 12-14 weeks before delivery date and the mill-direct schedule holds. Last-minute RFQs to stockists often result in 14-18 weeks anyway, with no chemistry control.
Q5. Can I bundle the order with related items to save logistics cost?
Yes — and you should. A typical USC or SMR secondary-side package includes: superheater / reheater tubes, economizer inlet tubes, heat efficiency tubes for the economizer, header pipe fittings (elbows, returns), pipe flanges (ASME B16.5 Class 600-1500), industrial valves (ASME B16.34 Class 600-1500), gasket stud bolt nut (ASME B16.20 + B16.21 + A193 + A194). A single bundled mill-direct RFQ that consolidates 5-7 of these categories typically saves 8-15 % on the total package vs ordering each separately. EZ Steel Industrial supplies all seven categories from the same mill yard with a single combined MTC and a single shipping window.
EZ Steel Industrial was founded in 1994 in Changsha, Hunan, China, and operates a 480,000+ t/year capacity covering carbon and carbon-alloy steel, stainless steel, copper and nickel alloy, heat-efficiency tubes, pipe fittings, pipe flanges, gaskets / stud bolts / nuts, and industrial valves. The mill is API / EN / ASME certified, ISO 9001 laboratory accredited, and ASME + AWS authorized.
For the high-temperature pressure-tube scope described in this guide, EZ Steel supplies:
Each shipment leaves the mill with a 3.1 MTC (or 3.2 for nuclear per RCC-M / ASME Section III), a 100 % ECT calibration record, the hydrostatic test log, and a heat-by-heat chemistry certificate. Independent third-party inspection (SGS / Bureau Veritas / TÜV / DNV) can be arranged on request for nuclear or high-pressure utility tenders.
Before you contact the mill, make sure your RFQ has these ten items, or the response will be slow and the quote will be rough.
For a 2026 USC, AUSC, PWR-retube, CSP-receiver, SMR-primary, or ethylene-cracker project, send the RFQ with the ten items above to:
EZ STEEL INDUSTRIAL
199 Xiangfu Road, Yuhua District, Changsha, Hunan, China
Tel: +86 731 8870 6116 | Email: export@ezsteelpipe.com
Website: https://www.ezindustrialtube.com/
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